Adhesive resins and laminate articles

ABSTRACT

Adhesive resins obtained by reacting 100 parts by weight of an epoxy-containing olefin polymer with 0.01-10 parts by weight of at least one ethylenically unsaturated fatty acid or derivative thereof, are described. The adhesive resins or olefin polymer compositions comprising the adhesive resins are particularly useful in lamination with other types of resins. Such laminates are also described.

BACKGROUND OF THE INVENTION

1. Field of the Invention

This invention relates to adhesive resins which have good adhesion tovarious other materials such as polyolefins, polyamides, polyesters,saponified ethylenevinyl acetate copolymers and metals, and also tolaminates using the same. More particularly, the invention relates toadhesive resins which are obtained by chemically combining 0.01-10 partsby weight of ethylenically unsaturated fatty acids or derivativesthereof with 100 parts by weight of epoxy group-containing olefinpolymers, and to laminates using such adhesive resins. The laminates areuseful as food wrap films or materials for food containers.

2. Description of the Prior Art

There have heretofore been proposed and used various types of laminateproducts which are made by laminating such materials as polyolefins,polyamides, polyesters, saponified ethylene-vinyl acetate copolymers ormetals with different kinds of materials so that one materialcompensates for the defect of another. For instance, laminates ofpolyolefins with polyamides or polyesters are known as good wrapmaterials. Because of their good transparency, flexibility, hygienicproperties and heat sealability, polyolefins have been wisely used aswrapping or packaging materials for foods. However, polyolefins have ashortcoming in that owing to their high permeability to gases such asoxygen, carbon dioxide and the like, they are unable to preserve foodsover a long term. On the other hand, although polyamides have goodresistance to heat and an oil, they are poor in vapor permeability andheat sealability. Polyesters or saponified ethylene-vinyl acetatecopolymers have low gas permeability and good heat resistance, but theyare disadvantageously poor in heat sealability. These disadvantages canbe overcome by lamination of polyolefins and these other materials.

However, lamination of these materials involves the drawback thatadhesion between these materials is poor, causing delamination or plyseparation to readily occur.

There have been conventionally proposed, as adhesive resins capable ofimproving the interlaminar bond strength, ethylene-vinyl acetatecopolymers, ionomer resins or polyolefin resins modified with maleicanhydride or the like (see, for example, Japanese Laid-open PatentApplication Nos. 51-92880, 52-32080, 54-82, 54-87753 and 54-160481).However, these resins have good compatibility with polyolefins orpolyamides and a fairly high interlaminar bond strength, but are not yetsatisfactory. In addition, the strength of adhesion to polyesters is notso high as to stand practical use.

SUMMARY OF THE INVENTION

It is accordingly an object of the present invention to provide adhesiveresins which overcome the drawbacks of the prior art resins.

It is another object of the invention to provide adhesive resins whichhave improved interlaminar bond strength with respect to polyolefin andpolyamide resins and have much improved adhesion to certain types oflow-adhesive resins like polyesters and saponified ethylene-vinylacetate copolymers.

It is a further object of the invention to provide various types oflaminates using the adhesive resins of the type mentioned above wherebyhigh interlaminar bond strength is ensured.

According to one embodiment of the invention, there is provided anadhesive resin which is obtained by reacting 100 parts by weight of anepoxy group-containing olefin polymer with 0.01-10 parts by weight of anethylenically unsaturated fatty acid or derivative thereof.

According to another embodiment of the invention, there is also provideda laminated article which comprises at least two layers. One layerconsists of an adhesive resin which is obtained by reacting 100 parts byweight of an epoxy group-containing olefin polymer with 0.01-10 parts byweight of at least one ethylenically unsaturated fatty acid orderivative thereof, or an olefin polymer composition comprising theadhesive resin. The other layer may be of a material selected fromthermoplastic resins, thermosetting resins, rubbers, metals, cloth,paper, wood or glass.

DETAILED DESCRIPTION AND EMBODIMENTS OF THE INVENTION

The epoxy group-containing olefin polymers used in the present inventionmay be copolymers of olefins and unsaturated glycidyl group-containingmonomers, and terpolymers or multi-polymers of olefins, unsaturatedglycidyl group-containing monomers and ethylenically unsaturatedmonomers. The olefins in the copolymers should preferably be ethylene.Preferable copolymers consist of 50-99.96 wt % of ethylene, 0.05-50 wt %of a glycidyl group-containing monomer, and 0-49.95 wt % of anethylenically unsaturated monomer.

Examples of the unsaturated glycidyl group-containing monomers includeglycidyl esters such as glycidyl acrylate, glycidyl methacrylate,monoglycidyl itaconate, monoglycidyl butenetricarboxylate, diglycidylbutenetricarboxylate, triglycidyl butenetricarboxylate, glycidyl estersof alpha-chloroallyl, maleic acid, crotonic acid, fumaric acid and thelike, glycidyl esters such as vinyl glycidyl ether, allyl glycidylether, 2-methylallyl glycidyl ether, glycidyloxyethyl vinyl ether,styrene-p-glycidyl ether and the like, and p-glycidylstyrene.Preferably, glycidyl methacrylate and acryl glycidyl ether arementioned.

The ethylenically unsaturated monomers of the invention may be at leastone monomer selected from olefins, vinyl esters, alpha,beta-ethylenically unsaturated carboxylic acids and derivatives thereof.Specific examples include olefins such as propylene, butene-1, hexene-1,decene-1, octene-1, styrene and the like, vinyl esters such as vinylacetate, vinyl propionate, vinyl benzoate and the like, acrylic acid,methacrylic acid and esters thereof such as methyl, ethyl, propyl,butyl, 2-ethylhexyl, cyclohexyl, dodecyl, octadecyl, acrylates ormethacrylates, maleic acid, maleic anhydride, itaconic acid, fumaricacid, maleic mono and diesters, vinyl chloride, vinyl ethers such asvinyl methyl ether, vinyl ethyl ether and the like, and acrylic amides.Of these, acrylates are preferred.

The epoxy group-containing olefin polymers are prepared according to ahigh pressure radical polymerization process in which 50-99.95 wt % ofethylene, 0.05-50 wt % of at least one unsaturated glycidylgroup-containing monomer, and 0-49.95 wt % of at least one otherethylenically unsaturated monomer are contacted simultaneously or in astepwise manner for polymerization in a vessel or tubular reactor in thepresence of 0.0001-1 wt % of a free radical catalyst, based on the totalweight of the monomers, and also in the presence of a chain transferagent and, if necessary, an aid under conditions of a polymerizationpressure of 500-4000 Kg/cm², preferably 1000-3500 Kg/cm² and a reactiontemperature of 50°-400° C., preferably 100°-350° C.

The free radical catalysts may be ordinary initiators such as peroxides,hydroperoxides, azo compounds, amine oxide compounds, oxygen and thelike.

The chain transfer agents include, for example, hydrogen, propylene,butene-1, saturated aliphatic hydrocarbons and halogenated hydrocarbonshaving 1-20 carbon atoms or a greater number of carbon atoms, e.g.methane, ethane, propane, butane, isobutane, n-hexane, n-heptane,cycloparaffins, chloroform, carbon tetrachloride, saturated aliphaticalcohols having 1-20 or greater carbon atoms, e.g. methanol, ethanol,propanol, isopropanol and the like, saturated aliphatic carbonylcompounds having 1-20 or greater carbon atoms, e.g. carbon dioxide,acetone, methyl ethyl ketone and the like, and aromatic compounds suchas toluene, diethylbenzene, xylene and the like.

The epoxy group-containing olefin polymers used in the present inventionmay be olefin homopolymers or copolymers modified by graft reactionthereto of the unsaturated glycidyl group-containing monomers.

The olefin polymers for these purposes are, for example, homopolymerssuch as low, medium and high density polyethylene, polypropylene,polybutene-1, poly-4-methylpentene-1 and the like, copolymers of a majorproportion of ethylene and other alpha-olefins such as ethylenepropylenecopolymers, ethylene-butene-1 copolymers, ethylene-hexene-1 copolymers,ethylene-4-methylpentene-1 copolymers, ethylene-octene-1 copolymers andthe like, copolymers of a major proportion of propylene and otheralpha-olefins such as propylene-ethylene block copolymers,ethylene-vinyl acetate copolymers, ethylene-acrylic acid copolymers,ethylene-methacrylic acid copolymers, copolymers of ethylene and methyl,ethyl, propyl, isopropyl and butyl esters of acrylic acid or methacrylicacid, ethylene-maleic acid copolymers, ethylene-propylene copolymerrubbers, ethylene-propylene-diene copolymer rubbers, liquidpolybutadiene, ethylene-vinyl acetate-vinyl chloride copolymers, andmixtures thereof. These polymers may be further mixed with other typesof synthetic resins or rubbers.

The ethylenically unsaturated fatty acids and derivatives thereof are,for example, acrylic acid, methacrylic acid, maleic acid, fumaric acid,itaconic acid, citraconic acid, maleic anhydride, citraconic anhydride,itaconic anhydride, methyl acrylate, methyl methacrylate, ethylacrylate, ethyl methacrylate, butyl acrylate, butyl methacrylate,monoethyl or diethyl maleate, acrylic amide, methacrylic amide, maleicmonoamide, sodium acrylate, sodium methacrylate, potassium acrylate,potassium methacrylate, and the like. Of these, maleic anhydride is mostpreferable.

In the practice of the invention, an ethylenically unsaturated fattyacid or derivative thereof is subjected to graft reaction with the epoxygroup-containing olefin polymer in the presence of a radical generator.

The graft reaction may be carried out by several methods including amethod using radical initiators, a method utilizing plasma, and a methodin which temperatures are raised to produce thermal radicals. Of these,the method using radical initiators is preferred because of theinexpensive apparatus, convenience and high reactivity.

The radical initiators may be organic peroxides and azo nitriles.Examples of the organic peroxides include ketone peroxides such asmethyl ethyl ketone peroxide, cyclohexane peroxide and the like, peroxyketals such as 1,1-bis(t-butylperoxy)-3,3,5-trimethylcyclohexane,1,1-bis(t-butylperoxy)cyclohexane and the like, hydroperoxides such ast-butyl hydroperoxide, cumene hydroperoxide, diisopropylbenzenehydroperoxide and the like, dialkyl peroxides such as di-t-butylperoxide, t-butyldicumyl peroxide, dicumyl peroxide,α,α'-bis(t-butylperoxyisopropyl)benzene,2,5-dimethyl-2,5-di(t-butylperoxy)hexane,2,5-dimethyl-2,5-di(t-butylperoxy)hexine-3 and the like, diacylperoxides such as benzoyl peroxide, octanoyl peroxide, decanoyl peroxideand the like, peroxydicarbonates such as diisopropyl peroxydicarbonate,di-n-propyl peroxydicarbonate and the like, and peroxy esters such ast-butyl peroxyacetate, t-butyl peroxyisobutylate, t-butyl peroxybenzoateand the like. Examples of azonitriles include azobisisobutyronitrile,azobisisopropionitrile and the like. These compounds are properlyselected depending on the reaction conditions such as reaction solvent,reaction temperature and the like.

The reaction using the radical initiators may be carried out by a numberof methods. For instance, there are mentioned a method in which thereaction is effected in the state of a solution using a medium which isa good solvent for epoxy group-containing olefin polymers (solutionreaction), a method in which the reaction is effected in the state of asuspension using a medium which is a poor solvent for epoxygroup-containing olefin polymers (suspension reaction), and a method inwhich the reaction is effected without use of any medium while heatingand mixing epoxy group-containing olefin polymers at temperatures higherthan the melting or softening point thereof (melt reaction). The mediumsused for the solution reaction include aliphatic hydrocarbons such ashexane, heptane, octane, cyclohexane, decaline and the like, aromatichydrocarbons such as benzene, toluene, xylene, tetralin and the like,and polar solvents such as dichlorobenzene, chloroform, carbondisulfide, carbon tetrachloride, trichloroethane and the like. Themediums suitable for the suspension reaction are, for example, water.For the melt reaction, it is usual to use extruders, kneaders, Banburymixers and rolls ordinarily used for processing of plastics or rubbers.The reaction conditions should be appropriately selected. The reactionshould be effected at temperatures which permit the olefin polymer tomelt and the radial initiator to sufficiently decompose within thereaction time. If the temperature is too high, epoxy group-containingolefin polymers or ethylenically unsaturated fatty acids may decompose,causing side reaction to occur. Accordingly, the temperature ispreferably in the range of approximately 100°-300° C.

The amount of addition of the ethylenically unsaturated fatty acid isselected from a range of 0.01-10 parts by weight, preferably 0.1-5 partsby weight, per 100 parts by weight of the epoxy group-containing olefinpolymer. If the amount is less than 0.01 part by weight, the adhesionstrength is not improved and thus the desired effect cannot be attained.On the other hand, when the amount exceeds 10 parts by weight, theresulting resin is colored or gelatin proceeds, thus causing foreignmatters to be unfavorably produced.

The adhesive resin obtained in the present invention may be used asadhesive resin compositions by mixing with polyolefins in desired mixingratio.

In the practice of the invention, both the unsaturated glycidylgroup-containing monomer and the ethylenically unsaturated fatty acidmay be added to the olefin polymer at the same time.

According to the second embodiment of the invention, the adhesive resinor an olefin polymer composition comprising the adhesive resin is usedfor lamination with other materials to obtain laminate articles havingat least two layers.

Other materials used in the present invention are thermoplastic resins,thermosetting resins, rubbers, metals, cloths, paper, wood and glass.

More particularly, such materials include: olefin polymers includinghomopolymers such as low, medium and high density polyethylene,polypropylene, polybutene-1, poly-4-methyl-pentene-1 and the like,copolymers of a major proportion of ethylene and other alpha-olefinssuch as, for example, ethylene-propylene copolymers, ethylene-butene-1copolymers, ethylene-hexene-1 copolymers, ethylene-4-methylpentene-1copolymers and the like, copolymers of a major proportion of propyleneand other alpha-olefins such as propylene-ethylene block copolymers,ethylene-vinyl acetate copolymers, ethylene-acrylic acid copolymers,ethylene-methacrylic acid copolymers, copolymers of ethylene and methyl,ethyl, propyl, isopropyl, butyl esters of acrylic of methacrylic acid,ethylene-maleic acid copolymers, ethylene-vinyl acetate-vinyl chloridecopolymers, and mixtures thereof; other thermoplastic resins includingsaponified ethylene-vinyl acetate copolymers, polyamide resins,polycarbonate resins, polyvinyl chloride resins, polyvinylidene chlorideresins, polyester resins, polyacrylonitrile resins, polystyrene resins,polyvinyl alcohol resins, ABS resins, polymethacrylates, fluorocarbonresins, polyimide resins, polyamideimide resins, polyether/ether ketoneresins, polyethersulfone resins, polysulfone resins, polyphenylene oxideresins, polyphenylene sulfide resins, polyacetal resins and mixturesthereof; thermosetting resins such as phenolic resins, urea resins,melamine resins and the like; and rubbers.

Examples of rubbers include synthetic rubbers such as polybutadiene,polyisoprene, neoprene rubber, ethylene-propylene copolymers,ethylene-propylene-diene copolymers, styrene-butadiene copolymer,styrene-acrylonitrile-butadiene copolymer, butyl rubber, polyurethanerubber, chlorosulfonated polyethylene, chlorinated polyethylene,fluororubbers, thiokol and the like, and natural rubbers.

Sheets of the synthetic resins or rubbers mixed with fillers may be alsoused in the present invention.

The fillers for these purposes include, for example, powdery andparticulate fillers such as calcium carbonate, magnesium carbonate,calcium sulfate, calcium silicate, clay, diatomaceous earth, talc,alumina, quartz sand, glass powder, iron oxide, metal powders, antimonytrioxide, graphite, silicon carbide, silicon nitride, silica, boronnitride, aluminum nitride, wood powder, carbon black and the like;plate-like or flaky fillers such as mica, glass, sericite, pyrophyllite,metal foils such as aluminum flake, graphite and the like; hollowfillers such as Shirasu balloons, metal balloons, glass balloons, pumicestone and the like; fibrous fillers such as glass fibers, carbon fibers,graphite fibers, whiskers, metal fibers, silicon carbide fibers, mineralfibers, e.g. asbestos and wollastonite, and organic fibers such asviscose, polyamide and vinylon fibers; and textile fillers such as glassfiber mats, organic fiber mats and the like.

Other substrate materials include metal foils, metal sheets, metalgauzes and punched plates of metals such as chromium, iron, nickel,zinc, tin, aluminum, copper, brass, galvanized steel and the like.

Cloths that can be employed as substrates include non-woven or wovenfabrics or nettings of fibers such as tape yarns and monofilamentsobtained from the thermoplastic resins indicated before, split filmsobtained by finely cutting films of the thermoplastic resins, wovenfabrics of synthetic fibers such as vinylon and tetron fibers or naturalfibers such as cotton, silk and hemp fibers, and woven fabrics, mats andfelts of fibers such as glass fibers, carbon fibers and metal fibers.

Paper sheets used as a substrate material may not be critical andinclude, for example, packaging papers such as kraft paper, roll paperand the like, thin papers such as glassine paper, paperboards and othermachine-made papers, Japanese papers such as shoji paper, and syntheticpapers such as polystyrene paper, vinylon paper and the like.

Examples of the multi-layer laminates using different types of materialsinclude polyester resin layer (hereinafter abbreviated as PET)/adhesiveresin layer (hereinafter abbreviated as MEGA)/high density polyethylenelayer (hereinafter abbreviated as HDPE), PET/MEGA/saponifiedethylene-vinyl acetate copolymer (hereinafter abbreviated as saponifiedEVA), PET/MEGA/aluminum, PET/MEGA/paper, PET/MEGA/PET,PET/MEGA/PET/ethylene-butene-1 copolymer (hereinafter abbreviated asLLDPE), and the like.

The method of making the laminated product is not critical and includes,for example, blown film extrusion using multi-layer dies, flat filmextrusion using T-dies, blow molding, injection molding, brushapplication, fluidized bed coating, powder spray coating, electrostaticcoating, press molding and the like.

In the practice of the invention, various forms of materials includingfilms, sheets, plates, bars, pipes, woven fabrics, and other processedarticles may be bonded.

Moreover, various additives may be used in the range of amount notimpeding the purposes of the invention. Examples of such additivesinclude antioxidants, UV absorbers, flame retardants, copperdeactivators, processability improvers, reinforcing agents, fillers,colorants, pigments, antistatic agents, antiblock agents, foaming agentsand the like.

The present invention is more particularly described by way of examplesand comparative examples.

EXAMPLES 1-2 <Preparation of Adhesive Resins>

1.7 kg of ethylene and 30 g of glycidyl methacrylate comonomer werecharged into a 3.8 liter autoclave, followed by copolymerizing in thepresence of di-tertiary-butyl peroxide under conditions of a pressure of1700 kg/cm² ·g and a temperature of 170° C., thereby obtaining 100 partsby weight of ethylene-glycidyl methacrylate copolymer (hereinafterreferred to simply as Et-GMA). This Et-GMA copolymer was subjected tograft reaction with 0.25 part by weight of maleic anhydride in aplastograph in the presence of 0.015 part by weight of dicumyl peroxideat a temperature of 190° C. for a reaction time of 7 minutes. Theresulting product (referred to simply as Et-GMA/MAn) was washed withacetone and made into a thin film, followed by quantitativedetermination of the amount of combined maleic anhydride by infraredspectroscopic analysis. The results are shown in Table 1 givenhereinafter.

The above procedure was repeated using a different amount of thecomonomer, thereby obtaining another adhesive resin. The results arealso shown in Table 1.

These adhesive resins were used for adhesion to PET and other substratematerials and the resulting laminates were subjected to measurement ofinterlaminar bond strength with the results shown in Table 1. Theinterlaminar bond strength was measured under the following conditions.

<Measuring Conditions>

PET, saponified EVA, HDPE and Al sheets, each having a thickness of 2mm, were each placed over an adhesive resin sheet having a thickness of1 mm, which was backed by a 50 μm thick Al foil for its reinforcement.The sheet assemblies were preheated for 5 minutes, and then pressedunder conditions of 240° C. and 50 kg/cm² ×5 minutes for PET and underconditions of 180° C. and 50 kg/cm² ×5 minutes for the other materials.Each laminate was subsequently cooled and cut to a width of 25 mm togive a test piece.

The test pieces were subjected to 180° peeling test at a pulling rate of50 mm/minute, and the values determined were given as the interlaminarbond strength.

EXAMPLE 3

The general procedure of Example 1 was repeated using, as thecomonomers, glycidyl methacrylate and ethyl acrylate to obtain aterpolymer of ethylene-glycidyl methacrylate-ethyl acrylate (hereinafterreferred to as Et-GMA-EA), followed by graft reaction in the same manneras in Example 1 to obtain a melic anhydride grafted polymer (hereinafterreferred to simply as Et-GMA-EA/MAn). Thereafter, an adhesion test wasconducted in the same mannner as in Examples. The results are shown inTable 1.

EXAMPLE 4

One hundred parts by weight of the adhesive resin obtained in Example 2was blended with 200 parts by weight of ethylene-ethyl acrylatecopolymer having an ethyl acrylate content of 19 wt % and a melt indexof 5.3 g/10 minutes. The blend was used for the adhesion test in thesame manner as in Example 1. The results are also shown in Table 1.

COMPARATIVE EXAMPLES 1-3

Ethylene-ethyl acrylate copolymer having an ethyl acrylate content of 19wt % and a melt index of 5.3 g/10 minutes, ethylene-vinyl acetatecopolymer having a vinyl acetate content of 15 wt % and a melt index of1.5 g/10 minutes (hereinafter referred simply as EVA), and maleicanhydride-modified low density polyethylene having a density of 0.92g/ml and a melt index of 1.0 g/10 minutes (trademark; N Polymer L6100,made by Nippon Petrochemical Co., Ltd.) (hereinafter referred to as NPolymer) were used, as adhesive resins, for adhesion to severalsubstrate materials in the same manner as in Example 1. The results areshown in Table 1.

                                      TABLE 1                                     __________________________________________________________________________                     Amount of                                                                     Comonomer    Bond Strength (kg/25 mm in width)               Example/                                                                             Adhesive  Combined                                                                             MI          Saponified                                Comp. Ex.                                                                            Resin     (wt %) (g/10 min.)                                                                         PET   EVA   HDPE  Al                            __________________________________________________________________________    Example 1                                                                            Et-GMA/MAn                                                                              GMA = 5.0                                                                            0.5   breakage of                                                                         13.0  breakage of                                                                         breakage of                                    MAn = 0.14   material    material                                                                            material                      Example 2                                                                            Et-GMA/MAn                                                                              GMA = 14.0                                                                           0.4   breakage of                                                                         13.5  breakage of                                                                         breakage of                                    MAn = 0.14   material    material                                                                            material                      Example 3                                                                            Et-GMA-EA/MAn                                                                           GMA = 5.1                                                                            0.3   breakage of                                                                         13.2  breakage of                                                                         breakage of                                    EA = 15      material    material                                                                            material                                       MAn = 0.14                                                   Example 4                                                                            Et-GMA/MAn +                                                                            GMA = 4.7                                                                            2.4   breakage of                                                                         13.1  breakage of                                                                         breakage of                          EEA blend MAn = 0.05   material    material                                                                            material                      Comp. Ex. 1                                                                          EEA       EA = 19                                                                              5.3   0.7    0.8  breakage of                                                                         9.7                                                                     material                            Comp. Ex. 2                                                                          EVA       VA = 15                                                                              1.5   0.7    0.8  breakage of                                                                         12.7                                                                    material                            Comp. Ex. 3                                                                          N Polymer --     1.0   1.5    5.0  breakage of                                                                         8.5                                                                     material                            __________________________________________________________________________

The adhesive resins of the invention have good adhesion force and wideutility in the field of coating on and lamination with other materials.They are applicable as a solution in solvent, or by a powder coatingmethod.

Thermoplastic resins including olefin polymers such as polyethylene,polypropylene, ethylene-alpha-olefin copolymers, ethylene-vinyl acetatecopolymers and the like may be added to the adhesive resins fordilution.

Laminated sheets, films, or other articles consisting of at least twolayers, one of which is made of the adhesive resin, have a highinterlaminar bond strength, and can also be readily heat-sealed withother types of materials. Three-layer or multi-layer laminates such asof PET/adhesive resin/polyolefin or saponified EVA make use of thecharacteristics of polyester, e.g. low gas permeability and highresistance to oil and heat, along with good characteristics of the othermaterials. These laminates will be utilized as food wrap films, foodpackaging bottles for mayonnaise, soy sauce, beer, carbonated drinks,oil and the like, films or bottles for wrapping medicines, and gasolinetanks.

What is claimed is:
 1. A laminate article comprising at least two layersformed by laminating at least one substrate material with a memberselected from an adhesive resin and an olefinic polymer compositioncontaining the same, the adhesive resin forming a layer in the resultinglaminate article and being obtained by chemically combining in thepresence of a radical initiator, 0.01-10 parts by weight of at least oneethylenically unsaturated fatty acid or derivative thereof with 100parts by weight of an epoxy group-containing olefin polymer prepared bysubjecting 50-99.95 wt. % of ethylene, 0.05-50 wt. % of at least oneunsaturated glycidyl group-containing monomer and up to 49.95 wt. % ofat least one other ethylenically unsaturated monomer, to high pressureradical polymerization.
 2. A laminate article according to claim 1,wherein said epoxy group-containing olefin polymer is a copolymer ofethylene and glycidyl acrylate or methacrylate, or a copolymer ofethylene, glycidyl acrylate or methacrylate and ethyl acrylate, and saidethylenically unsaturated fatty acid is maleic anhydride.
 3. A laminatearticle according to claim 1, wherein said substrate material is atleast one member selected from the group consisting of thermoplasticresins, thermosetting resins, rubbers, paper, wood, cloths, metals andglass.
 4. A laminate article according to claim 3, wherein thethermoplastic resin is at least one member selected from the groupconsisting of olefin resins, saponified ethylene-vinyl acetatecopolymers, polyamide resins, polycarbonate resins, polyvinyl chlorideresins, polyvinylidene chloride resins, polyester resins,polyacrylonitrile resins, polystyrene resins, polyvinyl alcohol resins,ABS resins, polymethyl methacrylate, fluorocarbon resins, polyimideresins, polyamide-imide resins, polyether.ether ketone resins, polyethersulfone resins, polysulfone resins, polyphenylene oxide resins,polyphenylene sulfide resins and polyacetal resins and blend thereof. 5.A laminate article according to claim 4, wherein said laminate articleconsists of a polyester resin, the adhesive resin and a saponifiedethylene-vinyl acetate resin arranged in this order.
 6. A laminatearticle according to claim 1, wherein the reaction between theethylenically unsaturated fatty acid and epoxy group containing olefinpolymer is carried out at a temperature 100°-300° C.
 7. A laminatearticle as in claim 6, wherein said temperature comprises about 190° C.